It's always a tough decision which technology to go for next. I usually opt for the ones that will help my tribe survive, and postpone the others until I have more people. It all depends on how you like to play the game (and how dangerously 'close to the edge' you like to be)!

Doctors only help villagers who are actually sick (and show that they are 'sick' on their details screen).
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Barbara
Unicorn
Last Day of Work