I know it sounds weird, but I would like to download the Main Theme song from the Virtual Villagers games(Not the 4 in-game songs mind you. Is this at all remotely possible for a Parrot head like me?

The music is not available for download, but you can find the .ogg files for each song in the game's Sounds folder. Of course, you need a player that can handle that open source audio format.

Aka Audacity

That is one of them, yes, but there are others, including a plugin for Windows Media Player or components for QuickTime, for people who don't want to install another application.

In that case I'd probably go for a plugin because the Audacity on my computer is somewhat unstable

Er, "Speaking of (unstable), Dr. who? Are they her at Princeton Plainsboro?